Page 295 - 1915, Springs of CA.
P. 295

SULPHUR  SPRINGS.                    275

      The springs were long known locally as Chittenden Sulphur Springs,
    but were  not improved  until  1909,  when  concrete  basins  were  con-
    structed  around  the  springs  and  the  property  opened  to  the  public
    as Shale Sulphur Springs.  Later the name was changed to El Pajaro.
      The following analyses of water from the Railroad Spring and the
    larger  of  the  White  Sulphur  Springs  show  them  to  be  secondary
    alkaline, primary saline waters:
           Analyses of water from El Pajaro Springs, Santa Cruz  County,  Cal.
                        [Constituents are in parts per million.]

                                    1           2            3
    Properties of reaction:
                                        37           31
                                         0            4
                                         0            0
                                         1            0
                                        62           65
                                   (?)          (?)
             Constituents.      By   Reacting   By   Reacting   By   Reacting
                               weight.  values.  weight.  values.  weight.  values.
    Sodium (Na).. ............................  199   8.63   159  6.94
                                  4.3   .11   4.5   .12
    T/ittmi m (T/i) .............................  0   .00   0   .00
                                 0      .00   0     .00
                                154    7.66   182   9.08
                                 83    6.81  84     6.88
    Iron(Fe).................................  .22  2.8   .10
    Aluminum (Al) ...........................  \   6.2
    Sulphate (864) ............................  150   3.12   234   4.85   85  1.77
    Chloride (Cl).. .................:..........  193  5.45   109   3.08
                                  .4    .02    .8   .05
                                402    13.41   392   13.07
                                 0      .00   0     .00
    Phosphate (PO*) ..........................  0  .00   0   .00
    Silica (Si02)..-... ....... ................  58  J.92  57  1.88
                               1,249.9      1,225.1
                              Present. Present. Present.  Present.
                                 4.8    .28   8.6   .50    28    1.67
    Methane (CH4).. ..........................  Present.  Present.
                               «In suspension.
     1.  Railroad Spring.  Analyst, Riddell and McCreary (1908).  Authority, owner of springs.
     2.  White Sulphur Spring.  Analyst, Riddell and McCreary' (1908).  Authority, owner of springs.
     3.  White Sulphur Spring.  Analyst and authority, F. M. Eaton (1909).
      The first two samples were analyzed  several weeks after they  were
    collected.  In order  to  determine, if  possible,  to what extent change
    had  taken  place  in  the  unstable  sulphur  compounds  between  the
    times  of  collection  and  analysis,  a  sample  from  the  White  Sulphur
    Spring  was  later  collected  in  a  bottle containing  iodine  solution, so
    that  the  sulphide  constituent  was  at  once  precipitated  as  sulphur
    according to the reaction H2S + 21 = 2HI + S and could be determined
    independently  of  the  sulphate  radicle.  The  sulphide  and  sulphate
    constituents were then determined within  a few days  of  the time of
    collection,  with  the  results  shown  in  the  analysis  by  F.  M.  Eaton.
    These  results  are  not  very  satisfactory,  however,  for  although  the
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